Professor Andrew Weller

Professor Weller will officially start in the Department of Chemistry on 2 January 2020.

Research

Research in the Weller group is based upon synthetic organometallic chemistry and catalysis, and in particular the generation and stabilisation of transition metal complexes with a low coordination number. These complexes often show very interesting, and novel, structures that display C–H, B–H and C–C bonding modes (via agostic or sigma interactions). Not only are we interested in the fundamentals of synthesis, bonding and structure of these complexes, but we also have a focus on their use and development in challenging catalytic bond transformations, such as C–H, B–H and C–C activation for the synthesis platform chemicals, new materials or fine chemicals. Collaborations with synthetic organic chemists (Professor Michael Willis, Oxford), computational chemists (Professor Stuart Macgregor, Heriot–Watt), experts in the study of mechanism using kinetics (Professor Guy Lloyd–Jones, Edinburgh) and novel analytical techniques (Professor J. S. McIndoe, University of Victoria), and Inorganic Materials Chemists (Professor Ian Manners, University of Victoria) also lead to a deeper understanding of structures and reactivity and applications of many of the new complexes and catalytic systems discovered.

Biography

Andrew Weller is a Professor of Chemistry at the University of York, moving with his group in January 2020. Prior to this position he was Professor of Chemistry at the University of Oxford, and a fellow of Magdalen College. He moved to Oxford in 2007, after starting his independent career at the University Bath in 1999 as a Royal Society University Research Fellow, promoted to Reader in 2004.

He completed his first degree at the University of Warwick, a PhD at Bristol (advised by Dr John Jeffery), and PDRA positions at Heriot–Watt (Professor Alan Welch) and Notre Dame (Professor Tom Fehlner).

Weller was the recipient of the inaugural Dalton Transactions European Lectureship award 2008. He was a 2013/14 Peter Wall Institute for Advanced Studies Visiting Scholar, UBC, Canada; in 2015 the Howard Fellow, University New South Wales, Australia, a visiting Professor at the University of Perugia, Italy and a Vielberth Fellowship at the University of Regensburg (2016). He is a currently holder of an EPSRC Established Career Fellowship (2015–2021) and was recipient of the Royal Society of Chemistry Frankland award in 2016. While at Oxford he was co–director of the recently funded EPSRC CDT in Inorganic Synthesis for Future Manufacturing (OxICFM).

 

Publications

ORCID ID: orcid.org/0000-0003-1646-8081

Selected Recent Publications

2019

E. A. K. Spearing-Ewyn, N. A. Beattie, A. L. Colebatch, A. J. Martinez-Martinez, A. Docker, T. M. Boyd, G. Baillie, R. Reed, S. A. Macgregor,* A. S. Weller* The Role of Neutral Rh(PONOP)H, free NMe2H, Boronium and Ammonium Salts in the Dehydrocoupling of Dimethylamine-borane using the Cationic Pincer [Rh(PONOP)(η2–H2)]+ Catalyst. Dalton Trans. 2019, in the press

A. I. McKay, A. J. Bukvic, B. E. Tegner, A. L. Burnage, A. J. Martinez-Martinez, N. H. Rees, S. A. Macgregor,* A. S. Weller* Room Temperature Acceptorless Alkane Dehydrogenation from Molecular σ–Alkane Complexes, J. Am. Chem. Soc. 2019141, 11700 [.pdf]

A. Johnson, A. J. Martínez-Martínez, S. A. Macgregor* and A. S. Weller* A d10 Ag(I) amine–borane σ–complex and comparison with a d8 Rh(I) analogue: structures on the η1 to η2η2 continuum. Dalton Trans. 201948, 9776. [.pdf]  (special issue to mark the IYPT)

M. Dietz, A. Johnson, A. Martínez–Martínez, A.S. Weller* The [Rh(Xantphos)]+ Catalyzed Hydroboration of Diphenylacetylene using Trimethyl Amine–Borane. Inorganica Chimica Acta 2019491, 9. [.pdf]  (Special issue to celebrate the contributions of M. L. H. Green)

G. M. Adams, D. E. Ryan, N. A. Beattie, A. I. McKay, G. C. Lloyd–Jones and A. S. Weller Dehydropolymerization of H3B·NMeH2 using a [Rh(DPEphos)]+ catalyst: the promoting effect of NMeH2, ACS Catalysis 20199, 3657. [.pdf

A. J. Martínez-Martínez* and A. S. Weller* Solvent-free Anhydrous Li+, Na+ and K+ salts of [B(3,5–(CF3)2C6H3)4]–, [BArF 4]–.Improved Synthesis and Solid-State Structures. Dalton Trans. 201948, 3551. [.pdf]  (special issue in honour of Professor Geoff Cloke)

A. L. Colebatch* and A. S. Weller* Amine-borane Dehydropolymerization: Challenges and Opportunities, Chem. Eur. J. 201925, 1379. [.pdf]  (invited contribution) 

2018

A. J. Martínez-Martínez, B. E. Tegner, A. I. McKay, A. J. Bukvic, N. H. Rees, G. J. Tizzard, S. J. Coles, M. R. Warren, S. A. Macgregor* and A. S. Weller* Modulation of σ-Alkane Interactions in [Rh(L2)(alkane)]+ Solid-State Molecular Organometallic (SMOM) Systems by Variation of the Chelating Phosphine and Alkane: Access to η2,η2-σ-Alkane Rh(I), η1-σ-Alkane Rh(III) Complexes, and Alkane Encapsulation. J. Am. Chem. Soc. 2018140, 14958. [.pdf

A. I. McKay, A. J. Martínez-Martínez, H. J. Griffiths, N. H. Rees, J. B. Waters, A. S. Weller,* T. Krämer, S. A. Macgregor* Controlling Structure and Reactivity in Cationic Solid–State Molecular OrganoMetallic (SMOM) Systems using Anion Templating. Organometallics 201837, 3524. [.pdf]

J. Barwick-Silk, S. Hardy, M. C. Willis and A. S. Weller* Rh(DPEPhos)-Catalyzed Alkyne Hydroacylation using β-Carbonyl Substituted Aldehydes. Mechanistic Insight Leads to Low Catalyst Loadings that Enables Selective Catalysis on Gram-Scale J. Am. Chem. Soc. 2018140, 7347. [.pdf]

I. Manners,* J.Turner, N. Chilton, A. Kumar, G. Whittell, A. Colebatch, H.l. Sparkes, A. Weller Iron Precatalysts with Bulky Tri(t‐butyl)cyclopentadienyl Ligands for the Dehydrocoupling of Dimethylamine‐Borane, Chem. Eur. J. 201853, 14127. [.pdf] "HOT" article

A. L. Colebatch, B. W. Hawkey Gilder, G. R. Whittell, N. L. Oldroyd, I. Manners and A. S. Weller* A General, Rhodium-Catalyzed, Synthesis of Deuterated Boranes and N-Methyl Polyaminoboranes, Chem. Eur. J. 201824, 5450. [.pdf] (Chosen as a "Hot" Article)

A. Grigoropoulos, A. I. McKay, A. P. Katsoulidis, R. P. Davies, A. Haynes, L. Brammer, J. Xiao, A. S. Weller* and M J. Rosseinsky* Encapsulation of Crabtree's catalyst in sulfonated MIL-101(Cr): enhancement of stability and selectivity between competing reaction pathways by the MOF chemical microenvironment Angew. Chem. Int. Ed. 201857, 4532. [.pdf]

G. M. Adams, A. L. Colebatch, J. T. Skornia, A. I. McKay, H. C. Johnson, G. C. Lloyd–Jones, S. A. Macgregor, N. A. Beattie, A.S. Weller* The Dehydropolymerization of H3B•NMeH2 to form Polyaminoboranes using [Rh(Xantphos–alkyl)] Catalysts. J. Am. Chem. Soc. 2018140, 1481. [.pdf]

G. M. Adams,* A. S. Weller* POP–Type Ligands: Variable Coordination and Hemilabile Behaviour Coord. Chem. Rev. 2018355, 150. [.pdf]

2017

F. M. Chadwick, A. I. McKay, A. J. Martinez–Martinez, N. H. Rees, T. Krämer, S. A. Macgregor* and A. S. Weller* Solid–State Molecular Organometallic Chemistry. Single–Crystal to Single–Crystal Reactivity and Catalysis with Light Hydrocarbon Substrates. Chem. Sci. 2017, 8, 6014. [.pdf]  (Chosen as a "Hot" Article)

T. J. Coxon, M. Fernández, J. Barwick-Silk, A. I. Mckay, L. E. Britton, A. S. Weller and M. C. Willis* Exploiting Carbonyl Groups to Control Intermolecular Rhodium-Catalyzed Alkene and Alkyne Hydroacylation J. Am. Chem. Soc. 2017, 139, 10142. [.pdf]

A. L. Colebatch, A. I. McKay, N. A. Beattie, S. A. Macgregor* and A. S. Weller* Fluoroarene Complexes with Small Bite Angle Bisphosphines: Routes to Amine−Borane and Aminoborylene Complexes Eur. J. Inorg. Chem. 2017, 4533. [.pdf] (Invited article for a special issue) 

X. Wang, T. N. Hooper, A. Kumar, l. K. Priest, Y. Sheng, T. O. M. Samuels, S. Wang, A. W. Robertson, M. Pacios, H. Bhaskaran, A. S. Weller*, J. H. Warner* Oligomeric Aminoborane Precursors for the Chemical Vapour Deposition Growth of Few-Layer Hexagonal Boron Nitride Cryst. Eng. Commun. 2017, 19, 285. [.pdf]

A. I. McKay, T. Krämer, N. H. Rees, A. L. Thompson, K. E. Christensen, S. A. Macgregor,* A. S. Weller,* Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF 4] Organometallics, 2017, 36, 22. [.pdf] (Invited article for a special issue on hydrocarbon activation) 

2016

F. M. Chadwick, T. Krämer, T. Gutmann, N. H. Rees, A. L. Thompson, A. J. Edwards, G. Buntkowsky, S. A. Macgregor,* and A. S. Weller* Selective C-H Activation at a Molecular Rhodium Sigma-Alkane Complex by Solid/Gas Single-Crystal to Single-Crystal H/D Exchange. J. Am. Chem. Soc. 2016, 138, 13369. [.pdf]

A. S. Weller*, F. M. Chadwick and A. I. McKay, Transition Metal Alkane Sigma–Complexes: Synthesis, Characterization and Reactivity, Adv. Organomet. Chem. 2016, 66, 223. [.pdf]

R. Theron, Y. Wu, L. P. E. Yunker, A. V. Hesketh, I. Pernik, A. S. Weller, J. S. McIndoe*, Simultaneous orthogonal methods for the real-time analysis of catalytic reactions, ACS Cat. 2016, 6, 6911. [.pdf]

A. Kumar, N. A. Beattie, S. D. Pike, S. A. Macgregor,* A. S. Weller* The Simplest Amino-borane H2B=NH2 Trapped on a Rhodium Dimer Angew. Chem. Int. Ed. 2016, 55, 6551. [.pdf]

M. W. Drover, E. G. Bowes, L. L. Schafer,* J. A. Love,* A S. Weller* Phosphoramidate-Supported Cp*Ir(III) Aminoborane H2B=NR2Complexes: Synthesis, Structure, and Solution Dynamics Chem. Eur. J. 2016, 22,6793. [.pdf]

A.Kumar, I. K. Priest, T.N. Hooper,* and A. S. Weller* Variable Coordination Modes and Catalytic Dehydrogenation of B-Phenyl Amine-Boranes, Dalton Trans 2016, 45, 6183. [.pdf]

F. M. Chadwick, N. H. Rees, A. S. Weller,* T. Krämer, M. Iannuzzi, S. A. Macgregor,* A Rh–pentane sigma–alkane complex. Characterization in the solid–state by experimental and computational techniques Angew. Chem. Int. Ed. 2016, 55, 3677. [.pdf]

T. N. Hooper, A. S. Weller*, N. A. Beattie and S. A. Macgregor* Dehydrocoupling of Phosphine-Boranes Using the [RhCp*Me(PMe3)(CH2Cl2)][BArF4] Precatalyst: Stoichiometric and Catalytic Studies Chem. Sci. 2016, 7, 2414. [.pdf]  (see here for published correction)

F. M. Chadwick, N. Olliff, A. S. Weller* A convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BArF4] and a comparison of reactivity with H2 in solution and the solid–state. J. Organomet. Chem. 2016, 812, 268. [.pdf]

A. Grigoropoulos, G. F. S. Whitehead, N. Perret, A. P. Katsoulidis, F. M. Chadwick, R P. Davies, A. Haynes, L. Brammer, A. S. Weller,* J. Xiao, Matthew J. Rosseinsky* Encapsulation of an organometallic cationic catalyst by direct exchange into an anionic MOF Chem. Sci. 2016, 7, 2037. [.pdf]

A. Kumar, J. S. A. Ishibashi, T. N. Hooper, T. C. Mikulas, D. A. Dixon, S.–Y. Liu* and AS. Weller* The Synthesis, Characterization and Dehydrogenation of Sigma–Complexes of BN–Cyclohexanes Chem. Eur. J. 2016, 22, 310. [.pdf]

Vacancies

For current PhD and PDRA opportunities see the main York Chemistry Pages.

Applications from suitably qualified and self-motivated PhD/PDRA level co-workers are welcomed. Please contact Andrew directly to discuss any opportunities further (andrew.weller@york.ac.uk).

 

Contact details

Prof. Andrew Weller
Professor in Inorganic Chemistry
Department of Chemistry
University of York
Heslington
York
YO10 5DD