RHaMBLe –Reactive Halogens in the Marine Boundary Layer

Gordon McFiggans (UMan), Martin Gallagher (UMan), Lucy Carpenter (UYork), John Plane (ULeeds), Dwayne Heard (ULeeds), William Bloss (ULeeds), Stephen Ball (ULeic)

 
RHaMBLe is an integrated programme aiming to quantify impacts of marine halogen emissions on atmospheric composition by the direct observation of a range reactive halogen species (RHS) in the marine atmosphere.  Emphasis is placed on the roles of halogens in oxidative processes and on secondary aerosol formation and transformations resulting from the cycling of RHS. RHaMBLe will extensively link to UK and internationally funded programmes to provide a package within UK SOLAS to link oceanic fluxes to atmospheric impacts.

 
RHaMBLe consists of two campaigns, one held in Roscoff, Brittany in July-August 2006 and the second in and around Cape Verde between 18th May and the 15th June 2007.   This webpage focuses on the second of these campaigns only.  Please contact Gordon McFiggans (g.mcfiggans@manchester.ac.uk) for details of the first campaign.
   (Proposal)

Ground-based measurements

 site photo


Ship measurements

Measurement Species

Instrument

Who to Contact

 

 

 

I2, OIO, IO (water column and atmospheric)

BBCEAS

Steve Ball, University of Leicester and ***, University of Cambridge

IO/OH/HO2

FAGE

Trevor Ingham/ Roisin Commane, University of Leeds

O3

2B UV absorption

Sarah Moller, University of York

NOx

chemiluminescence

Sarah Moller, University of York

Aerosol number and size distribution

3 nm-20 μm

SMPS (mobility), OPC and FSSP (optical instrumentation)

James Allan, University of Manchester

Halocarbons

2 x GC-MS

Charlotte Jones/Rachel Dunk, University of York

 

 

 

 Ship plan- “To quantify marine halocarbon emission variability and latitudinal variation, characterise in situ open ocean atmospheric reactive iodine latitudinal variability and characterise oxidative chemistry perturbation due to oceanic emission of halogens from the Mauritanian upwelling region”


Prevailing meteorological conditions will be used to direct the cruise in terms of geographical positioning and measurement interpretation particularly:-

                - Exploitation of any broad flow connection between Cape Verde and the ship to interpret measurements as process studies

                - Identification of in- and out-of plume conditions to contrast chemistry influenced and uninfluenced by emissions from the upwelling region.


                                Fig 1.  MODIS 3-day composite of chl-a concentration for 25th-27th May                    Fig 2. Cruise track (superimposed on a zoom of Fig 1)  


During this campaign there was also a small aircraft campaign running simultaneously implementing the NERC Dornier 228 aircraft.    (
Aircraft proposal)
The Dornier overflew the Discovery on the line of the first vertical gridline on Fig 2. 

 
Brief diary of events so far....

    11th May-17th May        Set-up week, Generator set-up for extra power at the site, instruments set-up on Discovery ship in Lisbon.

    18th May                       Measurements begin at the atmospheric site,  Discovery ship sets sail from Lisbon.

    25th May                       Ship docks in Mindelo, visits to the ground site and to the ship, buffet lunch, ship sails north and east towards Mauritanian upwelling.

                                        Aircraft campaign starts with a 3pm flight.

    26th May                       Flight over Discovery (The Dornier flew over the line marked by blue squares on Fig 2 above).

    27th May                       3 profile flights out from and above the atmospheric site,  9am, 1pm, 5pm.

    29th May                       Flight over Discovery (The Dornier flew over the Discovery just after the turning point marked by 149 11:00 on Fig 2 above).

    30th May                       3 profile flights.

    31st May                       3 profile flights.

    1st June                        3 profile flights.

    2nd June                       3 profile flights.

    3rd June                        Aircraft campaign finishes, ground and ship campaign continue.


ECMWF Trajectories (BADC)

8-day back trajectories for the ground-based site:-   18/05/07   00:00     06:00     12:00     18:00        
                                                                                19/05/07  
00:00     06:00     12:00     18:00
                                                                                20/05/07   00:00     06:00     12:00     18:00
                                                                                21/05/07   00:00     06:00     12:00     18:00
                                                                                22/05/07   00:00     06:00     12:00     18:00
                                                                                23/05/07   00:00     06:00     12:00     18:00
                                                                                24/05/07  
00:00     06:00     12:00     18:00

         Associated pressure plots:-                             18/05/07   00:00     06:00     12:00     18:00
                                                                                19/05/07  
00:00     06:00     12:00     18:00
                                                                                20/05/07   00:00     06:00     12:00     18:00
                                                                                21/05/07   00:00     06:00     12:00     18:00
                                                                                22/05/07   00:00     06:00     12:00     18:00
                                                                                23/05/07   00:00     06:00     12:00     18:00
                                                                                24/05/07  
00:00     06:00     12:00     18:00
  

All campaign back trajectories can be found here and here!
 

Data

Core Data from the site for campaign

More data


Campaign Photos

Aircraft photos courtesy of Jim McQuaid